Taken from the format help: /A:size Overrides the default allocation unit size. Default settings are strongly recommended for general use. NTFS supports 512, 1024, 2048, 4096, 8192, 16K, 32K, 64K. FAT supports 512, 1024, 2048, 4096, 8192, 16K, 32K, 64K, (128K, 256K for sector size > 512 bytes). FAT32 supports 512, 1024, 2048, 4096, 8192, 16K, 32K, 64K, (128K, 256K for sector size > 512 bytes).
Sounds to me like NTFS only supports sector sizes of 512; but, it doesn't answer why my master and model are 4096 on our 2005 server.